Stannous Chloride → HCID 68936914, compound

HRID 2218734Notes

Reaction equation

HRID 2218734 reaction equation
Cl[Sn]Cl.[CH3:4][O:5][C:6]1[C:11]2[O:12][CH2:13][C:14]3[CH:30]=[CH:29][CH:28]=[CH:27][C:15]=3[C:16](=[CH:17][C:18]3[CH:23]=[CH:22][CH:21]=[C:20]([N+:24]([O-])=O)[CH:19]=3)[C:10]=2[CH:9]=[CH:8][CH:7]=1>>[CH3:4][O:5][C:6]1[C:11]2[O:12][CH2:13][C:14]3[CH:30]=[CH:29][CH:28]=[CH:27][C:15]=3[C:16](=[CH:17][C:18]3[CH:19]=[C:20]([NH2:24])[CH:21]=[CH:22][CH:23]=3)[C:10]=2[CH:9]=[CH:8][CH:7]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 68935014HCID 68935014, compound

Product 1

HCID 68936914HCID 68936914, compound

Procedure

Prepare the title compound by SnCl2 reduction of 4-methoxy-11-(3-nitro-benzylidene)-6,11-dihydro-dibenzo[b,e]oxepine (from Example 270) to provide 267 mg of product (93.7% yield). This material is used without further characterization.

Sources & evidence

ORD record
ord-9bf02d93a12245b2859c91f4aa92d236
Source dataset
uspto-grants-2008_08
Patent number
US07411072B2

Reaction notes

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