Stannous Chloride → HCID 68936580, compound

HRID 2218737Notes

Reaction equation

HRID 2218737 reaction equation
Cl[Sn]Cl.[Cl:4][C:5]1[C:15]2[CH2:14][O:13][C:12]3[CH:16]=[CH:17][CH:18]=[CH:19][C:11]=3[C:10](=[CH:20][C:21]3[CH:26]=[CH:25][CH:24]=[C:23]([N+:27]([O-])=O)[CH:22]=3)[C:9]=2[CH:8]=[CH:7][CH:6]=1>>[Cl:4][C:5]1[C:15]2[CH2:14][O:13][C:12]3[CH:16]=[CH:17][CH:18]=[CH:19][C:11]=3[C:10](=[CH:20][C:21]3[CH:22]=[C:23]([NH2:27])[CH:24]=[CH:25][CH:26]=3)[C:9]=2[CH:8]=[CH:7][CH:6]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 68938368HCID 68938368, compound

Product 1

HCID 68936580HCID 68936580, compound

Procedure

Prepare the title compound by SnCl2 reduction of 7-chloro-11-(3-nitro-benzylidene)-6,11-dihydro-dibenzo[b,e]oxepine (from Example 272) to provide 900 mg (98%) of product.

Sources & evidence

ORD record
ord-8ff85aea943e48d8b6370a2325045fbd
Source dataset
uspto-grants-2008_08
Patent number
US07411072B2

Reaction notes

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