Acetic Acid → HCID 69152371, compound

HRID 2220739Notes

Reaction equation

HRID 2220739 reaction equation
S(C1C=CC(C)=CC=1)([O-])(=O)=O.[CH3:12][N+:13]1[CH:18]=[CH:17][C:16]([CH:19]=[C:20]([N+:22]([O-])=O)[CH3:21])=[CH:15][CH:14]=1.[CH3:25][C:26]([OH:28])=[O:27]>>[C:26]([OH:28])(=[O:27])[CH3:25].[CH3:21][CH:20]([NH2:22])[CH2:19][CH:16]1[CH2:15][CH2:14][N:13]([CH3:12])[CH2:18][CH2:17]1

Participants

3

Reactant 2

HCID 176Acetic AcidHCID 86596253HCID 86596253, compound

Product 1

HCID 69152371HCID 69152371, compound

Procedure

A mixture of 1-methyl-4-(2-nitro-propenyl)-pyridinium tosylate (66) and Pt2O (10 wt %) in AcOH was agitated under 50 psi of H2 (gas) for a time sufficient for reaction completion. The mixture was filtered through Celite and the solvent removed by rotary evaporation to afford compound 67.

Workup

  1. filtrationThe mixture was filtered through Celite
  2. customthe solvent removed by rotary evaporation

Sources & evidence

ORD record
ord-121272054dd348119ea5c972aa6d5d64
Source dataset
uspto-grants-2008_08
Patent number
US07417152B2

Reaction notes

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