HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → 2-Octanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | 2-Octanol | HCID 20083 | — |
| Reactant | 4-dodecyloxycarbonyl-N-hydroxyphthalimide | HCID 10915765 | — |
| Catalyst | Cobalt diacetate | HCID 6277 | — |
| Product | 2-Octanone | HCID 8093 | 6.3% |
Reaction Steps
A mixture of 24 mmol of 2-octanol, 0.1 mmol of 4-dodecyloxycarbonyl-N-hydroxyphthalimide and 0.005 mmol of cobalt(II) acetate was stirred at 70° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 3 hours and thereby yielded 1.52 mmol of 2-octanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07368615B2 |
| Source dataset | uspto-grants-2008_05 |
| ORD ID | ord-447589590b6b496d9940af4909374b60 |
| Source note | uspto-grants-2008_05 |