Methyl Ethyl Ketone → Cyclohexanone

HRID 2222050Notes

Reaction equation

[C:1]([O:5][CH2:6][C:7]([CH2:36][O:37][C:38](=[O:41])[CH:39]=[CH2:40])([CH2:14][O:15][CH2:16][C:17]([CH2:30][O:31]C(=O)C=C)([CH2:24][O:25][C:26](=[O:29])[CH:27]=[CH2:28])[CH2:18][O:19][C:20](=[O:23])[CH:21]=[CH2:22])[CH2:8][O:9][C:10](=[O:13])[CH:11]=[CH2:12])(=[O:4])[CH:2]=[CH2:3].[CH2:42]([C:44]([CH3:46])=[O:45])[CH3:43]>>[C:20]([O:19][CH2:18][C:17]([CH2:30][OH:31])([CH2:16][O:15][CH2:14][C:7]([CH2:8][O:9][C:10](=[O:13])[CH:11]=[CH2:12])([CH2:36][O:37][C:38](=[O:41])[CH:39]=[CH2:40])[CH2:6][O:5][C:1](=[O:4])[CH:2]=[CH2:3])[CH2:24][O:25][C:26](=[O:29])[CH:27]=[CH2:28])(=[O:23])[CH:21]=[CH2:22].[C:44]1(=[O:45])[CH2:46][CH2:2][CH2:1][CH2:43][CH2:42]1

Participants

Reactant 2

HCID 6569Methyl Ethyl Ketone3×

HCID 122409Dipentaerythritol hexaacrylate

Product 2

HCID 7967Cyclohexanone

HCID 108956Dipentaerythritol pentaacrylate

Procedure

To 315.0 g of a dipentaerythritol pentaacrylate and dipentaerythritol hexaacrylate mixture (DPHA, produced by Nippon Kayaku Co., Ltd.), 450.0 g of a methyl ethyl ketone dispersion solution of silica fine particle (MEK-ST, solid concentration: 30 mass %, produced by Nissan Chemicals Industries, Ltd.), 15.0 g of methyl ethyl ketone, 220.0 g of cyclohexanone and 16.0 g of a photopolymerization initiator (Irgacure 907, produced by Nippon Ciba Geigy) were added and stirred. The resulting solution was filtered through a polypropylene-made filter having a pore size of 0.4 μm to prepare a coating solution for hard coat layer.

Sources & evidence

ORD record: ord-c4b04ae80fe14bdd80e16d5d0fdfa6f4
Source dataset: uspto-grants-2008_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07371439B2

Reaction notes

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