Sulfonium → HCID 86605943, compound

Participants

Reaction Steps

9 g of dichloromethane and 1.0 g of sodium 2-(bicyclo[2.2.1]heptan-2-yl)-1,1,2,2-tetrafluoroethane sulfonate were added to 10 g of an aqueous solution of 1-(naphthalen-2-yl)tetrahydrothiopheniummethane sulfonate which was synthesized in the same manner as the sulfonium salt (A-1). The mixture was reacted while vigorously stirring for 12 hours using a magnetic stirrer. After the reaction, 10 g of dichloromethane was added. The organic layer was washed five times with 10 g of water and dried using 2 g of magnesium sulfate. The magnesium sulfate was then removed by filtration. The solvent was evaporated using a rotary evaporator to obtain 1.4 g of 1-(naphthalen-2-yl)tetrahydrothiophenium 2-(bicyclo[2.2.1]heptan-2-yl)-1,1,2,2-tetrafluoroethane sulfonate as a white solid.

Provenance & Evidence