Methanol → HCID 23089266, compound

HRID 2222054Notes

Reaction equation

HRID 2222054 reaction equation
CS([O-])(=O)=O.[CH:6]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[CH:8][C:7]=1[S+:16]1[CH2:20][CH2:19][CH2:18][CH2:17]1.CO.[F:23][C:24]([F:51])([S:47]([OH:50])(=[O:49])=[O:48])[C:25]([F:46])([F:45])[C:26]([F:44])([F:43])[C:27]([F:42])([F:41])[C:28]([F:40])([F:39])[C:29]([F:38])([F:37])[C:30]([F:36])([F:35])[C:31]([F:34])([F:33])[F:32]>O>[F:51][C:24]([F:23])([S:47]([O-:50])(=[O:49])=[O:48])[C:25]([F:45])([F:46])[C:26]([F:44])([F:43])[C:27]([F:41])([F:42])[C:28]([F:40])([F:39])[C:29]([F:38])([F:37])[C:30]([F:36])([F:35])[C:31]([F:34])([F:33])[F:32].[CH:6]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[CH:8][C:7]=1[S+:16]1[CH2:20][CH2:19][CH2:18][CH2:17]1

Participants

5

Reactant 3

HCID 887MethanolHCID 74483Perfluorooctanesulfonic acidHCID 23089289HCID 23089289, compound

Product 1

HCID 23089266HCID 23089266, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

6.0 g of 1-(naphthalen-2-yl)tetrahydrothiophenium methane sulfonate synthesized in the same manner as in Example 1 was added dropwise to 5.0 g of previously prepared 30 wt % methanol solution of perfluoro-n-octane sulfonic acid. After the addition, the reaction solution was poured into 50 g of water. White precipitate was collected by filtration, washed several times with water, and dried under vacuum to obtain 2.1 g of 1-(naphthalen-2-yl)tetrahydrothiophenium perfluoro-n-octane sulfonate as a white solid.

Workup

  1. additionAfter the addition
  2. filtrationWhite precipitate was collected by filtration
  3. washwashed several times with water
  4. customdried under vacuum

Sources & evidence

ORD record
ord-e1ca5411df664369ab3ae5c19d17e3a3
Source dataset
uspto-grants-2008_05
Patent number
US07371503B2

Reaction notes

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