HuagongsheHuagongshe Chemistry Print Report · For research reference only
(Z)-2-(3,4-dimethoxyphenyl)-3-(4-hydroxyphenyl)acrylonitrile → (E)-2-(3,4-dimethoxy-phenyl)-3-(4-hydroxy-phenyl)-acrylonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (Z)-2-(3,4-dimethoxyphenyl)-3-(4-hydroxyphenyl)acrylonitrile | HCID 10446442 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | (E)-2-(3,4-dimethoxy-phenyl)-3-(4-hydroxy-phenyl)-acrylonitrile | HCID 39149142 | 41% |
Reaction Steps
Compound 1 (100 mg) was dissolved in acetonitrile, and the resultant solution was subjected to photoreaction by use of a high-pressure mercury lamp. The resultant reaction mixture was concentrated to dryness under reduced pressure, followed by purification by use of a silica gel column, to thereby produce the target product (41 mg, yield: 41%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07371773B2 |
| Source dataset | uspto-grants-2008_05 |
| ORD ID | ord-89bde775fc994b5aa80b2fa5945a3ae0 |
| Source note | uspto-grants-2008_05 |