HRID2223864

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID81961

Triethyl ethane-1,1,2-tricarboxylate

C11H18O6

结构：CC(C)(C)[Si](OCCC1(CCI)CCCCC1)(c1ccccc1)c1ccccc1

HCID59714983

未命名化合物

PRODUCTS

生成物

结构：CCOC(=O)CC(CCC1(CCO[Si](c2ccccc2)(c2ccccc2)C(C)(C)C)CCCCC1)(C(=O)OCC)C(=O)OCC

HCID59714909

未命名化合物

收率 65.8%

PROCEDURE

实验过程

Using tert-butyl-[2-[1-(2-iodoethyl]cyclohexyl]ethoxy]diphenylsilane (1.77 g) and triethyl 1,1,2-ethanetricarboxylate (2.51 g), the title compound (1.43 g) was obtained in the same manner as in Preparation Example 3B-1. This product was subjected to the subsequent step without further purification.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b534cb28c74f46419cc539b644c13bd3
来源数据集: uspto-grants-2008_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07375115B2
来源说明: uspto-grants-2008_05

反应 SMILES

[C:1]([Si:5]([O:18][CH2:19][CH2:20][C:21]1([CH2:27][CH2:28]I)[CH2:26][CH2:25][CH2:24][CH2:23][CH2:22]1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)([CH3:4])([CH3:3])[CH3:2].[CH:30]([C:42]([O:44][CH2:45][CH3:46])=[O:43])([C:37]([O:39][CH2:40][CH3:41])=[O:38])[CH2:31][C:32]([O:34][CH2:35][CH3:36])=[O:33]>>[O:18]([CH2:19][CH2:20][C:21]1([CH2:27][CH2:28][C:30]([C:37]([O:39][CH2:40][CH3:41])=[O:38])([CH2:31][C:32]([O:34][CH2:35][CH3:36])=[O:33])[C:42]([O:44][CH2:45][CH3:46])=[O:43])[CH2:26][CH2:25][CH2:24][CH2:23][CH2:22]1)[Si:5]([C:1]([CH3:2])([CH3:4])[CH3:3])([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1