HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diisobutylaluminum hydride → HCID 69104921, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diisobutylaluminum hydride | HCID 14487 | — |
| Reactant | HCID 69105172 | HCID 69105172 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 69104921 | HCID 69104921 | — |
Reaction Steps
105 mg of 8β-(2,2-difluorovinyl)-3-methoxy-17β-(tetrahydropyran-2-yloxy)-estra-1,3,5(10),9(11)-tetraene was reacted according to general operating instructions 19 for ether cleavage with DIBAH/acid. The yield of colorless crystals with a melting point of 103-106° C. was 75 mg (93%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07378404B2 |
| Source dataset | uspto-grants-2008_05 |
| ORD ID | ord-770474406de04185bd0d2f93c88a7db2 |
| Source note | uspto-grants-2008_05 |