HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl 2-(2-phenyl-2-propylpentanoyl)malonate → Methyl 1-hydroxy-4,4-diisopentyl-3-oxo-3,4-dihydro-2-naphthalenecarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl 2-(2-phenyl-2-propylpentanoyl)malonate | HCID 11552281 | — |
| Reactant | Dimethyl 2-(2-isopentyl-5-methyl-2-phenylhexanoyl)malonate | HCID 69270654 | — |
| Product | Methyl 1-hydroxy-4,4-diisopentyl-3-oxo-3,4-dihydro-2-naphthalenecarboxylate | HCID 68874215 | — |
Reaction Steps
The title compound was prepared according to the procedure of Example 1F, substituting the product of Example 6E for the product of Example 1E. 1H NMR (300 MHz, CDCl3): δ 15.02 (d, J=4.04 Hz, 1 H), 8.21 (m, 1 H), 7.61 (m, 1 H), 7.41 (m, 2 H), 3.99 (s, 3 H), 2.26 (m, 2 H), 1.92 (m, 2 H), 1.30 (m, 2 H), 0.79 (m, 14 H), 0.47 (m, 2 H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07378414B2 |
| Source dataset | uspto-grants-2008_05 |
| ORD ID | ord-1e9d61ceccd640d9a731de9a37e5cb9d |
| Source note | uspto-grants-2008_05 |