Sodium sulfate decahydrate → HCID 178483796, Verbindung

HRID 2225546Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2225546
[CH3:1][C@@H:2]1[CH2:7][CH2:6][C@H:5]([NH:8][C:9](=O)[CH2:10][N:11]([CH3:13])[CH3:12])[CH2:4][CH2:3]1.[H-].[Al+3].[Li+].[H-].[H-].[H-].O.O.O.O.O.O.O.O.O.O.S([O-])([O-])(=O)=O.[Na+].[Na+]>C1COCC1>[CH3:12][N:11]([CH3:13])[CH2:10][CH2:9][NH:8][C@H:5]1[CH2:4][CH2:3][C@@H:2]([CH3:1])[CH2:7][CH2:6]1

Komponenten

5

Edukt 3

HCID 62649Sodium sulfate decahydrateHCID 21226445Aluminium lithium hydrideHCID 178483958HCID 178483958, Verbindung

Produkt 1

HCID 178483796HCID 178483796, VerbindungAusbeute 65 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

Using 4.8 g of N-(cis-4-methylcyclohexyl)-2-dimethylaminoacetamide (Example 109), 1.8 g of lithium aluminum hydride, 150 ml of THF, and 5 g of sodium sulfate decahydrate, a reaction similar to that performed in Example 78 was carried out. As a result, 2.9 g of N-(2-dimethylaminoethyl)-cis-4-methylcyclohexylamine was obtained as a colorless oil, which had the following physiochemical properties:

Aufarbeitung

  1. customa reaction similar to

Quellen und Nachweise

ORD-Eintrag
ord-b286a883b51c4e158b6a6e2d405e28ad
Quelldatensatz
uspto-grants-1994_09
Patentnummer
US05344845

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