(2-Methoxy-4-prop-2-enylphenyl) acetate → Coniferaldehyde

HRID 2225988Notes

Reaction equation

HRID 2225988 reaction equation
C([O:4][C:5]1[C:6]([O:14][CH3:15])=[CH:7][C:8]([CH2:11][CH:12]=[CH2:13])=[CH:9][CH:10]=1)(=O)C.C(OC1C(OC)=CC(CC=C)=CC=1)(=[O:34])CCCCCCC/C=C\CCCCCCCC>>[CH3:15][O:14][C:6]1[CH:7]=[C:8](/[CH:11]=[CH:12]/[CH:13]=[O:34])[CH:9]=[CH:10][C:5]=1[OH:4]

Participants

3

Reactant 2

HCID 7136(2-Methoxy-4-prop-2-enylphenyl) acetateHCID 67822934HCID 67822934, compound

Product 1

HCID 5280536ConiferaldehydeYield 58%

Procedure

If the procedure of Example 1 is followed, but 25 ppm of eugenol acetate are employed as inductor in place of eugenol oleate, and if the fungus Fusarium moniliforme DSM 764 is used, 252 mg of coniferyl aldehyde (58% of theory) are obtained.

Sources & evidence

ORD record
ord-ad0fc3ea83794b2aa18d8a5fb2e54250
Source dataset
uspto-grants-1994_09
Patent number
US05344994

Reaction notes

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