Tert-Butyl isocyanide → HCID 178459945, compound

HRID 2226084Notes

Reaction equation

HRID 2226084 reaction equation
[C:1]([N+:5]#[C-:6])([CH3:4])([CH3:3])[CH3:2].[F:7][C:8]([F:15])([F:14])[C:9]([O:12][Cu:13])([CH3:11])[CH3:10]>C1C=CC=CC=1>[F:7][C:8]([F:15])([F:14])[C:9]([O:12][Cu:13])([CH3:11])[CH3:10].[C:1]([N+:5]#[C-:6])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 23577Tert-Butyl isocyanideHCID 178459944HCID 178459944, compound

Product 1

HCID 178459945HCID 178459945, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

An equimolar quantity of t-butyl isonitrile was added to 3.5 g of 2-trifluoromethylpropan-2-oxy-copper prepared according to Example 2 in benzene. The mixture was stirred further until the suspended solid had completely dissolved. Then readily volatile constituents were evaporated. The yield of 2-trifluoromethylpropan-2-oxy-copper-t-butyl isonitrile was approximately quantitative.

Workup

  1. customprepared
  2. dissolutionhad completely dissolved
  3. customThen readily volatile constituents were evaporated

Sources & evidence

ORD record
ord-bd7f214812fb4431b46a47e5df92c3ce
Source dataset
uspto-grants-1994_09
Patent number
US05346730

Reaction notes

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