((4-(tert-Butyl)phenyl)ethynyl)trimethylsilane → Trimethylsilyl[4-(4-methylpentyl)]phenylethyne

HRID 2226716Notes

Reaction equation

HRID 2226716 reaction equation
[CH3:1][Si:2]([C:5]#[C:6][C:7]1[CH:12]=[CH:11][C:10]([C:13]([CH3:16])(C)C)=[CH:9][CH:8]=1)([CH3:4])[CH3:3].[CH3:17][CH:18]([CH3:29])[CH2:19]CCC1C=CC(Br)=CC=1>>[CH3:4][Si:2]([C:5]#[C:6][C:7]1[CH:8]=[CH:9][C:10]([CH2:13][CH2:16][CH2:17][CH:18]([CH3:29])[CH3:19])=[CH:11][CH:12]=1)([CH3:1])[CH3:3]

Participants

3

Reactant 2

HCID 14989664((4-(tert-Butyl)phenyl)ethynyl)trimethylsilaneHCID 224090934-(4-Methylpentyl)bromobenzene2×

Product 1

HCID 54327813Trimethylsilyl[4-(4-methylpentyl)]phenylethyne

Procedure

Using the same general procedure as described for Compound 23, but using instead 4-(4-methylpentyl) bromobenzene (Compound 32), the title copound was synthesized as a colorless oil. PMR (CDCl3): δ0.32 (9H, s), 0.93 (6H, d, J~6.6 Hz), 1.18-1.29 (2H, m), 1.52-1.70 (3H, m), 2.58 (2H, t, J~7.7 Hz), 7.12 (2H, d, J~8.1 Hz), 7.43 (2H, d, J~8.1 Hz).

Workup

  1. customthe title copound was synthesized as a colorless oil

Sources & evidence

ORD record
ord-9266b366a59e49f7b4088cb09f1a166b
Source dataset
uspto-grants-1994_09
Patent number
US05349105

Reaction notes

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