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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2227600Generated: October 30, 2026

Benzyl mercaptan → HCID 86588936, compound

https://huagongshe.com/reaction/2227600

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzyl mercaptanHCID 7509—
ReactantBenzene, 1-chloro-4-ethynyl-HCID 70118—
ReactantSodiumHCID 5360545—
ProductHCID 86588936HCID 86588936—

Reaction Steps

A solution of 4-chlorophenylacetylene (0.02 mol) and benzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to the General Procedure to form Z-4-chlorostyryl benzylsulfide. The title compound was obtained in 74% yield following oxidation. 1HNMR (CDCl3) δ 4.55 (2H, s), 6.66 (1H, d, JH,H=12.12), 7.16-7.65 (9H aromatic+1H ethylenic).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06414034B1
Source datasetuspto-grants-2002_07
ORD IDord-7adf3f0fd84143628546f3f0a45546f4
Source noteuspto-grants-2002_07