Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | Oxalic Acid | HCID 971 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Vanadium | HCID 23990 | — |
| Reactant | Ammonium metavanadate [UN2859] [Poison] | HCID 62684 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 178526028 | HCID 178526028 | — |
Reaction Steps
A vanadium ammonium oxalate solution was prepared by adding ammonia and oxalic acid to ammonium polyvanadate suspended in water. The solution obtained contained 9.4% by weight of vanadium, measured as metal. The carriers obtained in Examples 1-3 were impregnated with the solution and subsequently calcined at 450° C. The catalysts obtained contained 4% by weight of vanadium, calculated as the metal, and contained the titania in the anatase form. The catalysts prepared from the carriers of Examples 1-3 are indicated as catalysts 1-3, respectively. Of the catalysts, 150 mg of the sieve fraction of 0.4-0.6 mm was tested at 140° C. and a pressure of 1 bar using a gas containing 900 ppm NO, 800 ppm NH3, 5% oxygen, 11% water and the remainder being argon. The gas flow was 45 ml/min. The products were analyzed with the help of a mass spectrometer.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06419889B1 |
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| Source dataset | uspto-grants-2002_07 |
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| ORD ID | ord-2dbb0bc02c9942da84dd05c877125f27 |
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| Source note | uspto-grants-2002_07 |
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