Diethyl Ether → HCID 178460955, compound

Participants

Reaction Steps

8.6 g (50 mmol) of compound II were dissolved in 250 ml of diethyl ether. At room temperature and with stirring, 11.1 g (72 mmol) of allyldichlorosilane (compound III) were added to this mixture, which was then stirred at room temperature for a further 3 h. The solvent was subsequently completely removed under reduced pressure and the residue was taken up in 200 ml of petroleum ether. The lithium chloride was centrifuged off, the supernatant was concentrated to a volume of about 20 ml and the reaction product was crystallized at −78° C. The yield was 8.59 g (60.4%).

Provenance & Evidence