HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Peroxide → HCID 22507636, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | Sodium Sulfite | HCID 24437 | — |
| Reactant | Octadecanoic acid, 1-hydroxy-2,2,6,6-tetramethyl-4-piperidinyl ester | HCID 580171 | — |
| Reactant | 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine | HCID 21885088 | — |
| Solvent | tert-Butanol | HCID 6386 | — |
| Product | HCID 22507636 | HCID 22507636 | — |
Reaction Steps
Aqueous hydrogen peroxide is added to a mixture of 4-octadecanoyloxy-1-oxyl-2,2,6,6-tetramethylpiperidine and ferrous chloride tetrahydrate in tert-butyl alcohol at 30-50° C. Excess peroxide is decomposed with aqueous sodium sulfite solution. The organic layer is concentrated to obtain a mixture which includes 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and the title compound. The title compound is separated from the mixture by high pressure liquid chromatography.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06420562B2 |
| Source dataset | uspto-grants-2002_07 |
| ORD ID | ord-d053f1d3f2a348419c5ac207b77ec5dc |
| Source note | uspto-grants-2002_07 |