HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Naphthoic acid → 1-Naphthalenecarbonyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Naphthoic acid | HCID 6847 | — |
| Reactant | Oxalyl chloride | HCID 65578 | — |
| Catalyst | Dimethylformamide | HCID 6228 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1-Naphthalenecarbonyl chloride | HCID 70146 | 100.2% |
Reaction Steps
a mixture of 17.2 g (0.1 mole) 1-naphthoic acid, 14 g (0.11 moles) oxalyl chloride, 150 ml methylene chloride and three drops DMF (dimethylformamide) were stirred for about 24 hours. The clear reaction mixture was stripped to give about 19.1 g of the 1-naphthoyl chloride as a brown liquid which was used in step (b) without further isolation.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04785019 |
| Source dataset | uspto-grants-1988_11 |
| ORD ID | ord-9fe9bb9855324c47a2866a607ad2f820 |
| Source note | uspto-grants-1988_11 |