HuagongsheHuagongshe Chemistry Print Report · For research reference only
4,4'-Diaminodicyclohexylmethane → 1,1-Diphenylmethanediamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4,4'-Diaminodicyclohexylmethane | HCID 15660 | — |
| Reactant | 1,1-Dicyclohexylmethanediamine | HCID 177095 | — |
| Product | 1,1-Diphenylmethanediamine | HCID 3036810 | — |
Reaction Steps
Instead of the pure 4,4'-diaminodicyclohexylmethane, mixtures of the diaminodicyclohexylmethane position isomers which are composed of 70 to 99 mol % of the 4,4'-diamino isomer, 1-30 mol % of the 2,4'-diamino isomer, 0-2 mol % of the 2,2'-diamino isomer and, if appropriate, diamines with a correspondingly higher degree of condensation and which are obtained by hydrogenation of diaminodiphenylmethane of technical quality can also be used. Up to 30% of the isophthalic acid can be replaced by terephthalic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04785050 |
| Source dataset | uspto-grants-1988_11 |
| ORD ID | ord-e58b4806614847f7a0de1abe48e5ef30 |
| Source note | uspto-grants-1988_11 |