HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Diiodoethane → HCID 21283714, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Diiodoethane | HCID 12224 | — |
| Reactant | 2-(2-Thienyl)thiazole | HCID 547510 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 21283714 | HCID 21283714 | 60.8% |
Reaction Steps
In a manner similar to Step C of Example 1, the reaction of 3.8 grams of (0.023 mole) of 2-(thien-2-yl)thiazole with 10.0 ml of a 2.5M solution of n-butyllithium in hexanes and 6.5 grams (0.023 mole) of 1,2-diiodoethane in 60 ml of diethyl ether yielded 4.1 grams of 5-iodo-2-(thien-2-yl)thiazole as a solid, m.p. 117°-119° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04788207 |
| Source dataset | uspto-grants-1988_11 |
| ORD ID | ord-52fa3fd27a60431b82da6e9701982857 |
| Source note | uspto-grants-1988_11 |