Thionyl Chloride → HCID 21283572, compound

HRID 2232532Notes

Reaction equation

HRID 2232532 reaction equation
S(Cl)([Cl:3])=O.[C:5]1([C:11]2[CH:12]=[C:13]([CH2:21]O)[C:14]3[C:19]([CH:20]=2)=[CH:18][CH:17]=[CH:16][CH:15]=3)[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1>C(Cl)(Cl)Cl>[Cl:3][CH2:21][C:13]1[C:14]2[C:19](=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:20]=[C:11]([C:5]2[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=2)[CH:12]=1

Participants

4

Reactant 2

HCID 24386Thionyl ChlorideHCID 21283567HCID 21283567, compound

Product 1

HCID 21283572HCID 21283572, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Thionyl chloride (0.78 cc) is added in the course of 10 minutes to a stirred solution, cooled beforehand to 0° C., of 3-phenyl-1-naphthalenemethanol (1 g) in chloroform (20 cc), and the temperature is then allowed to rise to room temperature (approximately 20° C.). The mixture is stirred for 15 hours at this temperature and the solvent evaporated under reduced pressure. 1-Chloromethyl-3-phenylnaphthalene (1.1 g) is obtained, the proton NMR spectrum of which, in deuterated chloroform, shows the following characteristics:

Workup

  1. customto rise to room temperature
  2. custom(approximately 20° C.)
  3. customthe solvent evaporated under reduced pressure

Sources & evidence

ORD record
ord-792870417b1348bd9b3cac1f7674e925
Source dataset
uspto-grants-1988_11
Patent number
US04788199

Reaction notes

Loading…