HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic acid, 2-(triphenylphosphoranylidene)-, methyl ester → HCID 86742583, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic acid, 2-(triphenylphosphoranylidene)-, methyl ester | HCID 17453 | — |
| Reactant | HCID 14994121 | HCID 14994121 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 86742583 | HCID 86742583 | — |
Reaction Steps
As described in Example 99, (E)-3-(3-fluorophenyl)-2-octenal (5.43 g was treated with (carbomethoxymethylene)triphenylphosphorane (9 g) in dichloromethane (50 mL) for 4 days at room temperature. The ester was isolated in the usual manner and purified by HPLC (ether-hexane; 1:9) to provide 6.04 g of (E,E)-5-(3-fluorophenyl)-2,4-decadienoic acid methyl ester as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04788206 |
| Source dataset | uspto-grants-1988_11 |
| ORD ID | ord-e3ff2c7a9d2b454a9e865d3aae38814f |
| Source note | uspto-grants-1988_11 |