Dibutylchlorophosphine → HCID 23317613, compound

HRID 2234273Notes

Reaction equation

HRID 2234273 reaction equation
[C:1]12([P:11]([C:16]34CC5CC(C[CH:18]([CH2:19]5)[CH2:17]3)C4)[CH2:12][CH2:13][CH2:14][CH3:15])[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.C12([Mg]Br)CC3CC(CC(C3)C1)C2.ClP(CCCC)CCCC>>[C:1]12([P:11]([CH2:16][CH2:17][CH2:18][CH3:19])[CH2:12][CH2:13][CH2:14][CH3:15])[CH2:8][CH:7]3[CH2:6][CH:5]([CH2:4][CH:3]([CH2:9]3)[CH2:2]1)[CH2:10]2

Participants

4

Reactant 3

HCID 305896DibutylchlorophosphineHCID 11371790Bis(adamantan-1-yl)(butyl)phosphaneHCID 178419608HCID 178419608, compound

Product 1

HCID 23317613HCID 23317613, compound

Procedure

di-1-Adamantyl-n-butylphosphine was procured from Strem, 77672 Kehl, Germany; 1-adamantyldi-n-butylphosphine was prepared from adamantylmagnesium bromide (J. Org. Chem. 47 1982 4120-4128) and chlorodi-n-butylphosphine (from Aldrich, 82018 Taufkirchen, Germany).

Sources & evidence

ORD record
ord-9e1d0e5770ca4ac0ad571aa22c38de07
Source dataset
uspto-grants-2010_05
Patent number
US07709680B2

Reaction notes

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