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[6-(Hydroxymethyl)pyridin-3-yl]methanol → 5-(Hydroxymethyl)pyridine-2-carboxaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | [6-(Hydroxymethyl)pyridin-3-yl]methanol | HCID 820251 | — |
| 触媒 | HCID 178418406 | HCID 178418406 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | 5-(Hydroxymethyl)pyridine-2-carboxaldehyde | HCID 13518562 | — |
反応手順
2,5-Di(hydroxymethyl)pyridine (10 g.) in 300 ml. of hot chloroform is treated with 100 g. of manganese dioxide. After 1/2 hour of stirring, the mixture is filtered and the filtrate is evaporated to dryness to give 2-formyl-5-hydroxymethylpyridine.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04355034 |
| 出典データセット | uspto-grants-1982_10 |
| ORD ID | ord-8ddc5fa0d3c247c6a795acbf315c6dcf |
| 出典メモ | uspto-grants-1982_10 |