HuagongsheHuagongshe Chemistry Print Report · For research reference only
1H-indol-4-ylmethanol → Indole-4-carboxaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1H-indol-4-ylmethanol | HCID 2773457 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | Indole-4-carboxaldehyde | HCID 333703 | 89.9% |
Reaction Steps
To a dissolved solution of (1H-Indol-4-yl)-methanol (100 mg, 0.69 mmole) in dichloromethane (0.500 ml), manganese (IV) oxide (597 mg, 6.9 mmol) is added. The reaction mixture stirred at room temperature for 8 hours and then passed through Celite. The reaction mixture is then concentrated to give a yellow oil (90 mg). MS (ESI) m/z 146.1 (M+1).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07713994B2 |
| Source dataset | uspto-grants-2010_05 |
| ORD ID | ord-bec4b63fe9b145b1abe04cc47ee81ac2 |
| Source note | uspto-grants-2010_05 |