Acetone → Methyl 7-hydroxy-2,2-dimethylbenzo[d][1,3]dioxole-5-carboxylate

HRID 2236682Notes

Reaction equation

[C:1]([O:12][CH3:13])(=[O:11])[C:2]1[CH:10]=[C:8]([OH:9])[C:6]([OH:7])=[C:4]([OH:5])[CH:3]=1.[CH3:14][C:15]([CH3:17])=O>>[CH3:13][O:12][C:1]([C:2]1[CH:3]=[C:4]([OH:5])[C:6]2[O:7][C:15]([CH3:17])([CH3:14])[O:9][C:8]=2[CH:10]=1)=[O:11]

Participants

Reactant 2

HCID 180Acetone

HCID 7428Methyl Gallate

Product 1

HCID 14016863Methyl 7-hydroxy-2,2-dimethylbenzo[d][1,3]dioxole-5-carboxylate

Procedure

7-Hydroxy-2,2-dimethyl-benzo[1,3]dioxole-5-carboxylic acid methyl ester is prepared from methyl gallate and acetone according to Percec, Virgil; Bera, Tushar K.; Tetrahedron; 58; 20; 2002; 4031-4040.

Sources & evidence

ORD record: ord-0ea31703ac43415a887341f87f98d459
Source dataset: uspto-grants-2010_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07713994B2

Reaction notes

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