HRID223696

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID962

Water

H2O

2 次

结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C

HCID5997

Cholesterol

C27H46O

$结构：CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[Na+]$

HCID23665730

Sodium oleate

C18H33NaO2

PRODUCTS

生成物

HCID5997

Cholesterol

C27H46O

$结构：CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[Na+]$

HCID23665730

Sodium oleate

C18H33NaO2

$结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C.CCCCCCCC/C=C\CCCCCCCC(=O)[O-].O.[Na+]$

HCID86738608

未命名化合物

PROCEDURE

实验过程

The following compositions of sodium oleate, cholesterol and water were prepared by adding the indicated quantity of sodium oleate in water to the cholesterol crystals and equilibrating for 48 hours. The resulting compositions were examined for the development of liquid crystals. Liquid crystal micelle systems of sodium oleate-cholesterol-water were formed from the compositions falling within the area indicated by A, B, C, D, E on the phase diagram of the drawing. These compositions are Nos. 7-11, 13-17, and 19-24.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b93778bba5c4488ca2686bb355c37e58
来源数据集: uspto-grants-1982_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04356167
来源说明: uspto-grants-1982_10

反应 SMILES

[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[Na+:21].[CH3:22][CH:23]([CH2:25][CH2:26][CH2:27][C@H:28]([C@@H:30]1[C@:48]2([CH3:49])[C@H:33]([C@H:34]3[C@H:45]([CH2:46][CH2:47]2)[C@:43]2([CH3:44])[C:37]([CH2:38][C@H:39]([CH2:41][CH2:42]2)[OH:40])=[CH:36][CH2:35]3)[CH2:32][CH2:31]1)[CH3:29])[CH3:24].[OH2:50]>>[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[Na+:21].[CH3:24][CH:23]([CH2:25][CH2:26][CH2:27][C@H:28]([C@@H:30]1[C@:48]2([CH3:49])[C@H:33]([C@H:34]3[C@H:45]([CH2:46][CH2:47]2)[C@:43]2([CH3:44])[C:37]([CH2:38][C@H:39]([CH2:41][CH2:42]2)[OH:40])=[CH:36][CH2:35]3)[CH2:32][CH2:31]1)[CH3:29])[CH3:22].[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[Na+:21].[CH3:24][CH:23]([CH2:25][CH2:26][CH2:27][C@H:28]([C@@H:30]1[C@:48]2([CH3:49])[C@H:33]([C@H:34]3[C@H:45]([CH2:46][CH2:47]2)[C@:43]2([CH3:44])[C:37]([CH2:38][C@H:39]([CH2:41][CH2:42]2)[OH:40])=[CH:36][CH2:35]3)[CH2:32][CH2:31]1)[CH3:29])[CH3:22].[OH2:50]