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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 22372Erstellt: 25. Oktober 2026

5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalene-2-carbonyl chloride → Methyl 4-methyl-3-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphtoylthio)benzoate

https://huagongshe.com/reaction/22372

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalene-2-carbonyl chlorideHCID 2795466—
EduktMethyl 3-mercapto-4-methyl benzoateHCID 13633551—
LösungsmittelTriethylamineHCID 8471—
ProduktMethyl 4-methyl-3-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphtoylthio)benzoateHCID 1363356388,3%

Reaktionsschritte

In a manner analogous to Example 1(a), starting with 1.83 g (10 mmol) of methyl 3-mercapto-4-methyl benzoate, 1.5 ml of triethylamine and 2.76 g (11 mmol) of 5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphtoyl chloride, methyl 4-methyl-3-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphtoylthio)-benzoate (3.50 g; 88%) is produced.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05428052
Quelldatensatzuspto-grants-1995_06
ORD IDord-ce226f6565bb422a9d2595aa4ecabfee
Quellennotizuspto-grants-1995_06