Undecane → Pentylbenzene

HRID 2237319Notes

Reaction equation

HRID 2237319 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]>CC1CCCCC1.C1C[C@H]2[C@H]([C@H]3C[C@@H]2CC3)C1.C1C2C3C4C5C6CC4C(C56)C3C(C2)C1>[CH2:7]([C:6]1[CH:1]=[CH:2][CH:3]=[CH:4][CH:5]=1)[CH2:8][CH2:9][CH2:10][CH3:11].[CH3:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

4

Reactant 1

HCID 14257Undecane

Product 2

HCID 10864PentylbenzeneHCID 14257Undecane

Reagents, catalysts & solvents 1

HCID 568408964,7-Methano-2,3,8-methenocyclopent(a)indene, dodecahydro-, stereoisome r, mixt. with methylcyclohexane and (3aalpha,4beta,7beta,7aalpha)-octa hydro-4,7-methano-1H-indeneSolvent

Procedure

Running Reaction 2 at a 25% conversion of n-undecane gives the desired molar ratios of n-pentylbenzene and n-undecane in the synthetic JP-8 surrogate for mass and energy balance purposes:

Sources & evidence

ORD record
ord-426967893a1144ada0ccf8eb60002d82
Source dataset
uspto-grants-2010_05
Patent number
US07718051B2

Reaction notes

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