Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1-Butanol | HCID 263 | — |
| Reactant | Toluene | HCID 1140 | — |
| Reactant | Methyl acetoacetate | HCID 7757 | — |
| Reactant | Butyl acetoacetate | HCID 11576 | — |
| Catalyst | Bis(eta-cyclopentadienyl) iron | HCID 7611 | — |
| Product | alpha-Pinene oxide | HCID 91508 | — |
Reaction Steps
2.1 mL of methylacetoacetate (20 mmol) and 1.8 mL of n-butanol (20 mmol) were added into 20 mL of toluene and stirred at 30° C. and 400 rpm for 15 minutes. 155 mg of the catalyst (FerlipaseCB(7) polymer beads) prepared in (2) was added into the mixture to initiate reaction. A clear liquid sample was periodically sampled and analyzed using gas chromatography to identify n-butyl acetoacetate, which was the reaction product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07718128B2 |
|---|
| Source dataset | uspto-grants-2010_05 |
|---|
| ORD ID | ord-f66c520568724693ac4d1ecaa6a91dee |
|---|
| Source note | uspto-grants-2010_05 |
|---|
