Sodium Hydroxide → HCID 86615282, compound

HRID 2237341Notes

Reaction equation

HRID 2237341 reaction equation
FC(F)(F)C(F)(F)C(F)(F)C(F)(F)S([O-])(=O)=O.[C:18]1([CH3:39])[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[S+:24]1[C:37]2[C:32](=[CH:33][CH:34]=[CH:35][CH:36]=2)[C:31](=[O:38])[C:30]2[CH:29]=[CH:28][CH:27]=[CH:26][C:25]1=2.[OH-].[Na+].[F:42][C:43]([F:59])([F:58])[C:44]1[CH:45]=[C:46]([S:54]([OH:57])(=[O:56])=[O:55])[CH:47]=[C:48]([C:50]([F:53])([F:52])[F:51])[CH:49]=1>CO.O>[F:53][C:50]([F:51])([F:52])[C:48]1[CH:47]=[C:46]([S:54]([O-:57])(=[O:56])=[O:55])[CH:45]=[C:44]([C:43]([F:59])([F:42])[F:58])[CH:49]=1.[C:18]1([CH3:39])[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[S+:24]1[C:25]2[C:30](=[CH:29][CH:28]=[CH:27][CH:26]=2)[C:31](=[O:38])[C:32]2[CH:33]=[CH:34][CH:35]=[CH:36][C:37]1=2

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 17857395HCID 17857395, compoundHCID 86615284HCID 86615284, compound2×

Product 1

HCID 86615282HCID 86615282, compoundYield 114.5%

Reagents, catalysts & solvents 1

HCID 22242641Methanol--water (1/1)Solvent

Procedure

This compound was synthesized using 1.5 g of 10-tolyl-9-oxothioxanthenium nonafluorobutanesulfonate (Z-1) obtained in Synthesis Example 1. 10-Tolyl-9-oxothioxanthenium nonafluorobutanesulfonate (1.5 g) was dissolved in a methanol/water (=1/1) solution, and the resulting solution was passed through an ion exchange resin (Amberlite IRA402C1 in which the anion is replaced by OH with use of aqueous NaOH). After adding 1 g of 3,5-bistrifluoromethylbenzenesulfonic acid thereto, the solution was extracted with chloroform to obtain 1.7 g of 10-tolyl-9-oxothioxanthenium 3,5-bistrifluoromethylbenzene-sulfonate (Z-2) as a compound changed in the counter salt.

Workup

  1. customThis compound was synthesized
  2. customobtained in Synthesis Example 1
  3. extractionthe solution was extracted with chloroform

Sources & evidence

ORD record
ord-c657b750ccff41fd8cae970acd64e364
Source dataset
uspto-grants-2010_05
Patent number
US07718344B2

Reaction notes

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