Ammonia → HCID 54147581, compound

HRID 223739Notes

Reaction equation

HRID 223739 reaction equation
C([S:4][CH2:5][CH2:6][C:7]([N:9]1[CH2:16][C:15]([CH2:18][CH:19]=[CH2:20])([OH:17])[CH2:14][C@H:10]1[C:11]([OH:13])=[O:12])=[O:8])(=O)C.N>>[CH2:18]([C:15]1([OH:17])[CH2:16][N:9]([C:7](=[O:8])[CH2:6][CH2:5][SH:4])[C@H:10]([C:11]([OH:13])=[O:12])[CH2:14]1)[CH:19]=[CH2:20]

Participants

3

Reactant 2

HCID 222AmmoniaHCID 54528209HCID 54528209, compound

Product 1

HCID 54147581HCID 54147581, compound

Procedure

The product from part (b) is treated with concentrated ammonia according to the procedure of Example 2 to yield 4-allyl-4-hydroxy-1-(3-mercapto-1-oxopropyl)-L-proline.

Sources & evidence

ORD record
ord-eb62c10d7f4444e99457cafde9baa2c9
Source dataset
uspto-grants-1982_10
Patent number
US04356182

Reaction notes

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