Ammonia → HCID 57037162, compound

HRID 223740Notes

Reaction equation

HRID 223740 reaction equation
C([S:4][CH2:5][CH2:6][C:7]([N:9]1[CH2:13][C:12]([CH2:14][CH:15]=[CH2:16])=[CH:11][C@H:10]1[C:17]([OH:19])=[O:18])=[O:8])(=O)C.N>>[CH2:14]([C:12]1[CH2:13][N:9]([C:7](=[O:8])[CH2:6][CH2:5][SH:4])[C@H:10]([C:17]([OH:19])=[O:18])[CH:11]=1)[CH:15]=[CH2:16]

Participants

3

Reactant 2

HCID 222AmmoniaHCID 57306325HCID 57306325, compound

Product 1

HCID 57037162HCID 57037162, compound

Procedure

The product from part (b) is treated with concentrated ammonia according to the procedure of Example 4 to yield (2S)-4-allyl-2,5-dihydro-1-(3-mercapto-1-oxopropyl)-1H-pyrrole-2-carboxylic acid.

Sources & evidence

ORD record
ord-28c16d9263c6483c9cd9c1c975eceb08
Source dataset
uspto-grants-1982_10
Patent number
US04356182

Reaction notes

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