HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Hydroxide → 1-Dodecyl-2-(2-pyridyl)imidazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 1-Iododecane | HCID 16314 | — |
| Reactant | 1-Iodododecane | HCID 20282 | — |
| Reactant | 2-(1H-imidazol-2-yl)pyridine | HCID 589313 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 1-Dodecyl-2-(2-pyridyl)imidazole | HCID 20520763 | 103.7% |
Reaction Steps
A mixture of 14.5 g (0.1 mole) 2-(2-pyridyl)imidazole, 6 g (0.11 mole) ground KOH, 30 g (0.1 mole) iodododecane in about 150 ml of acetonitrile was stirred and refluxed for about 2 hours. The iododecane gradually went into solution as the reaction proceeded. After the 2 hours the reaction mixture was cooled and filtered. The resulting residue was extracted with hexane to give 32.5 g of crude product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04356309 |
| Source dataset | uspto-grants-1982_10 |
| ORD ID | ord-71aaab8d01e14499bd40051edaaf5053 |
| Source note | uspto-grants-1982_10 |