HCID 86738258, compound → HCID 13613310, compound

HRID 223822Notes

Reaction equation

HRID 223822 reaction equation
ClC1C(Cl)=C(OCC(OC(C)(C)C)=O)C=C2C=1C1C(CC)(C2)CCC(=O)C=1.[Cl:28][C:29]1[C:41]([Cl:42])=[C:40]([O:43][CH2:44][C:45]([O:47]C(C)(C)C)=[O:46])[CH:39]=[C:38]2[C:30]=1[C:31]1[C:36]([CH2:52][CH2:53][CH3:54])([CH2:37]2)[CH2:35][CH2:34][C:33](=[O:55])[CH:32]=1>>[Cl:28][C:29]1[C:41]([Cl:42])=[C:40]([O:43][CH2:44][C:45]([OH:47])=[O:46])[CH:39]=[C:38]2[C:30]=1[C:31]1[C:36]([CH2:52][CH2:53][CH3:54])([CH2:37]2)[CH2:35][CH2:34][C:33](=[O:55])[CH:32]=1

Participants

3

Reactant 2

HCID 86738258HCID 86738258, compoundHCID 86738259HCID 86738259, compound

Product 1

HCID 13613310HCID 13613310, compound

Procedure

Carrying out a reaction as described in Example 53, Step B, except that the tert.-butyl [(5,6-dichloro-9a-ethyl-3-oxo-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetate is replaced by an equimolar amount of tert.-butyl [(5,6-dichloro-3-oxo-9a-propyl-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetate, thereby is obtained [(5,6-dichloro-3-oxo-9a-propyl-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetic acid.

Workup

  1. customCarrying out a reaction

Sources & evidence

ORD record
ord-a365f9f2c5ad4ca5a14e39fcab79e494
Source dataset
uspto-grants-1982_10
Patent number
US04356314

Reaction notes

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