I, Disulfonimide → HCID 21177664, compound

HRID 2238339Notes

Reaction equation

[C:1]1([S:7]([N:10]=[C:11]2[CH:16]=[CH:15][C:14](=[N:17][S:18]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)(=[O:20])=[O:19])[CH:13]=[CH:12]2)(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Cl[NH:28][S:29]([C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=1)(=[O:31])=[O:30].[Na]>>[C:1]1([S:7]([NH:10][C:11]2[C:12](=[N:10][S:7]([C:1]3[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=3)(=[O:9])=[O:8])[CH:13]=[C:14]([NH:17][S:18]([C:21]3[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=3)(=[O:20])=[O:19])[C:15](=[N:28][S:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)(=[O:31])=[O:30])[CH:16]=2)(=[O:8])=[O:9])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

Reactant 2

HCID 231857I, Disulfonimide

HCID 24188389127-52-6

Product 1

HCID 21177664HCID 21177664, compound

Procedure

N,N′-Bis[phenylsulfonyl]-1,4-benzoquinone diimine is sulfanylamidated by sodium N-chlorobenzenesulfonamide to form 2,5-bis(phenylsulfonylamino)-N,N′-bis(phenylsulfonyl)-1,4-benzoquinone diimine. Similarly, amidation of N,N′-bis[phenylsulfonyl]-1,4-benzoquinone diimine with N-chloroamides gives the corresponding sulfonyl benzoquinone diimine derivatives in one step.

Sources & evidence

ORD record: ord-f265c8c2bcd24403a7b0e24c1d620657
Source dataset: uspto-grants-2010_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07718722B2

Reaction notes

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