2,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoyl fluoride → HCID 11294668, compound

HRID 2239193Notes

Reaction equation

HRID 2239193 reaction equation
F[C:2]([C:4]([O:10][C:11]([C:14]([C:17]([F:20])([F:19])[F:18])([F:16])[F:15])([F:13])[F:12])([C:6]([F:9])([F:8])[F:7])[F:5])=[O:3].[F:21][S:22]([CH2:25][CH2:26][O:27][CH2:28][CH2:29][OH:30])(=[O:24])=[O:23]>>[F:21][S:22]([CH2:25][CH2:26][O:27][CH2:28][CH2:29][O:30][C:2]([C:4]([O:10][C:11]([C:14]([C:17]([F:18])([F:19])[F:20])([F:15])[F:16])([F:12])[F:13])([C:6]([F:9])([F:8])[F:7])[F:5])=[O:3])(=[O:24])=[O:23]

Participants

3

Reactant 2

HCID 1027402,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoyl fluorideHCID 11378763Ethanesulfonyl fluoride, 2-(2-hydroxyethoxy)-

Product 1

HCID 11294668HCID 11294668, compound

Procedure

FCOCF(CF3)OCF2CF2CF3 obtained in Example 4 was reacted with FSO2CH2CH2OCH2CH2OH under the same conditions as in the above esterification to obtain FSO2CH2CH2OCH2CH2OCOCF(CF3)OCF2CF2CF3. The obtained FSO2CH2CH2OCH2CH2OCOCF(CF3)OCF2CF2CF3 was fluorinated under the same conditions as in the above fluorination step to obtain FSO2CF2CF2OCF2CF2OCOCF(CF3)OCF2CF2CF3. The obtained FSO2CF2CF2OCF2CF2OCOCF(CF3)OCF2CF2CF3 was decomposed under the same conditions as in the above decomposition step to obtain FSO2CF2CF2OCF2COF and FCOCF(CF3)OCF2CF2CF3.

Sources & evidence

ORD record
ord-f8b69b552ce2425ca3cd9d19e9162cb2
Source dataset
uspto-grants-2010_05
Patent number
USRE041357E1

Reaction notes

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