[(1Z)-2-Nitroprop-1-en-1-yl]benzene → 2-Nitropropylbenzene

HRID 2239209Notes

Reaction equation

HRID 2239209 reaction equation
[N+:1](/[C:4](=[CH:6]\[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)/[CH3:5])([O-:3])=[O:2]>O>[N+:1]([CH:4]([CH2:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)[CH3:5])([O-:3])=[O:2]

Participants

3

Reactant 1

HCID 699484[(1Z)-2-Nitroprop-1-en-1-yl]benzene

Product 1

HCID 865462-NitropropylbenzeneYield 41%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Z-2-nitro-3-phenyl-2-propene (151 mg 1 mmol) was reacted with yeast (5 g) and water (5 ml) according to Method I. The product was isolated as a racemic mixture of products in 41% yield. Reaction according to method II also resulted in a racemic mixture of products in 38% yield.

Workup

  1. customThe product was isolated as a racemic mixture of products in 41% yield
  2. customReaction
  3. customalso resulted in a racemic mixture of products in 38% yield

Sources & evidence

ORD record
ord-d5687bdc0ea04a45acaad14643d0fda6
Source dataset
uspto-grants-2010_05
Patent number
US07723065B2

Reaction notes

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