Dimethylthiocarbamoyl chloride → HCID 59305855, compound

Participants

Reaction Steps

To a solution of 25.38 g (0.15 mol) of N-hydroxy-hexahydrophthalimide (prepared as described in Chem. Pharm. Bull., 16, (1968), 622) and 0.5 g 4-dimethylaminopyridine in 100 ml pyridine were added 18.54 g (0.15 mol) of dimethylthiocarbamoyl chloride. The mixture was stirred at room temperature during 3 h and then poured into 1000 ml of ice water. The precipitate was filtered off and recrystallized from 120 ml of ethanol to give 28.38 g of white crystals, mp. 124-126° C.

Provenance & Evidence