Methanol → 4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononan-1-ol

HRID 2241018Notes

Reaction equation

HRID 2241018 reaction equation
[C:1]([CH:20]=[CH2:21])([C:4]([C:7]([C:10]([C:13]([C:16]([F:19])([F:18])[F:17])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].[CH3:22][OH:23]>>[C:1]([CH2:20][CH2:21][CH2:22][OH:23])([C:4]([C:7]([C:10]([C:13]([C:16]([F:17])([F:18])[F:19])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2]

Participants

3

Reactant 2

HCID 887MethanolHCID 91384(Perfluorohexyl)ethylene

Product 1

HCID 27761814,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononan-1-ol

Procedure

After confirming disappearance of C6F13CH═CH2 by gas chromatography, the reaction was terminated by cooling to obtain a reaction liquid. From the obtained reaction liquid, majority of methanol was distilled off under reduced pressure, and then, the reaction liquid was washed with water to remove the remaining methanol thereby to obtain 430 g of C6F13CH2CH2CH2OH having a purity of 92.8%.

Workup

  1. customthe reaction was terminated
  2. temperatureby cooling
  3. customto obtain
  4. customa reaction liquid
  5. distillationwas distilled off under reduced pressure
  6. customthe reaction liquid
  7. washwas washed with water
  8. customto remove the remaining methanol

Sources & evidence

ORD record
ord-47e7e307f8fb4c03878f21ad56b3f51c
Source dataset
uspto-grants-2010_05
Patent number
US07723439B2

Reaction notes

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