HRID2241062

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID81984

2-Hydroxy-2-methylpropiophenone

C10H12O2

结构：COc1cccc(OC)c1C(=O)P(=O)(CC(C)CC(C)(C)C)C(=O)c1c(OC)cccc1OC

HCID164459

Methanone, 1,1'-[(2,4,4-trimethylpentyl)phosphinylidene]bis[1-(2,6-dimethoxyphenyl)-

C26H35O7P

PRODUCTS

生成物

HCID164459

Methanone, 1,1'-[(2,4,4-trimethylpentyl)phosphinylidene]bis[1-(2,6-dimethoxyphenyl)-

C26H35O7P

结构：O=C(c1ccccc1C1(O)CCCCC1)c1ccccc1C1(O)CCCCC1

HCID19989408

未命名化合物

PROCEDURE

实验过程

Specifically, for example, IRUGACURE-1700 (brand name, which is produced by Chiba specialty chemical Co., Ltd.) in which 2-hydroxy-2-methyl-1-phenyl propane-1-on (Dacrocur 1173, brand name, which is produced by Chiba specialty chemical Co., Ltd.) and bis(2,6-dimethoxy benzoyl)-2,4,4-trimethyl pentyl phosphine oxide (product, which is produced by Chiba specialty chemical Co., Ltd.) are mixed at a rate of 75%:25%; IRUGACURE-1800 (brand name, which is produced by Chiba specialty chemical Co., Ltd.) in which 1-hydroxy-cyclohexyl-phenyl-ketone (IRUGACURE-184, brand name, which is produced by Chiba specialty chemical Co., Ltd.) and bis(2,6-dimethoxy benzoyl)-2,4,4-trimethyl pentyl phosphine oxide (product, which is produced by Chiba specialty chemical Co., Ltd.) are mixed at a rate of 75%:25%; IRUGACURE-1850 (brand name, which is produced by Chiba specialty chemical Co., Ltd.) in which the same components are mixed at a rate of 50%:50%; bis(2,4,6)-trimethyl benzoyl)-phenyl phosphine oxide (IRUGACURE-819, brand name, which is produced by Chiba specialty chemical Co., Ltd.); 2,4,6-trimethyl benzoyl-diphenyl phosphine oxide (Lucirin TPO, brand name, which is produced by BASF Co., Ltd.), and Darocur-4265 (brand name, which is produced by Chiba specialty chemical Co., Ltd.) in which 2-hydroxy-2-methyl-1-phenyl propane-1-on (Dacrocur 1173, brand name, which is produced by Chiba specialty chemical Co., Ltd.) and 2,4,6-trimethyl benzoyl-diphenyl phosphine oxide (Lucirin TPO, brand name, which is produced by BASF Co., Ltd.) are mixed at a rate of 50%:50% are exemplary.

WORKUP

后处理

additionare mixed at a rate of 75%

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d8ead8f5c2434d77af77678a2d573c56
来源数据集: uspto-grants-2010_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07723445B2
来源说明: uspto-grants-2010_05

反应 SMILES

O[C:2]([CH3:12])([CH3:11])[C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:4].[CH3:13][O:14][C:15]1[CH:44]=[CH:43][CH:42]=[C:41]([O:45][CH3:46])[C:16]=1[C:17]([P:19](=[O:40])([C:28](=[O:39])[C:29]1[C:34]([O:35][CH3:36])=[CH:33][CH:32]=[CH:31][C:30]=1[O:37][CH3:38])[CH2:20][CH:21]([CH3:27])[CH2:22][C:23]([CH3:26])([CH3:25])[CH3:24])=[O:18]>>[OH:14][C:15]1([C:11]2[CH:22]=[CH:21][CH:20]=[CH:12][C:2]=2[C:3]([C:5]2[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=2[C:15]2([OH:14])[CH2:44][CH2:43][CH2:42][CH2:41][CH2:16]2)=[O:4])[CH2:44][CH2:43][CH2:42][CH2:41][CH2:16]1.[CH3:13][O:14][C:15]1[CH:44]=[CH:43][CH:42]=[C:41]([O:45][CH3:46])[C:16]=1[C:17]([P:19](=[O:40])([C:28](=[O:39])[C:29]1[C:30]([O:37][CH3:38])=[CH:31][CH:32]=[CH:33][C:34]=1[O:35][CH3:36])[CH2:20][CH:21]([CH3:27])[CH2:22][C:23]([CH3:26])([CH3:25])[CH3:24])=[O:18]