HCID 131727931, compound → HCID 131727930, compound

HRID 2242769Notes

Reaction equation

HRID 2242769 reaction equation
[OH:1][CH:2]=[C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([N:9]([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[C:4]1=[CH:22][OH:23]>C(O)CCC>[CH2:2]([O:1][CH:2]=[C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([N:9]([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[C:10]2[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=2)[C:4]1=[CH:22][O:23][CH2:15][CH2:10][CH2:11][CH3:12])[CH2:3][CH2:4][CH3:5]

Participants

3

Reactant 1

HCID 131727931HCID 131727931, compound

Product 1

HCID 131727930HCID 131727930, compound

Reagents, catalysts & solvents 1

HCID 2631-ButanolSolvent

Procedure

A mixture of di(hydroxymethylene)-triphenylamine (0.25 g), butanol (1 g) and an ion exchange resin AMBERYST® 15 (0.05 g) was shaken at room temperature (about 23° C.) until the reaction was completed as indicated by thin layer chromatography (TLC). The mixture was filtered to remove the AMBERLYST 15 catalyst. Removal of the solvent under reduced pressure yielded charge transport compound (1). The structure was confirmed by 1H NMR spectrum.

Workup

  1. filtrationThe mixture was filtered
  2. customto remove the AMBERLYST 15 catalyst
  3. customRemoval of the solvent under reduced pressure
  4. customyielded

Sources & evidence

ORD record
ord-30388f1ced41482783ca4f3b03e81de3
Source dataset
uspto-grants-2010_03
Patent number
US07674565B2

Reaction notes

Loading…