HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphorus tribromide → Methyl 2-bromo-2-(3-methoxyphenyl)acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphorus tribromide | HCID 24614 | — |
| Reactant | Methyl 2-hydroxy-2-(3-methoxyphenyl)acetate | HCID 296017 | — |
| Product | Methyl 2-bromo-2-(3-methoxyphenyl)acetate | HCID 289522 | — |
Reaction Steps
Methyl-m-methoxymandelate is reacted with phosphorous tribromide by the method of I. P. Beletskaya, Zh. Obshch. Khim., 34, 321 (1964) to give methyl bromo-(m-methoxyphenyl)acetate as a pale yellow liquid, and used below (without further purification).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04231935 |
| Source dataset | uspto-grants-1980_11 |
| ORD ID | ord-4ecdd6d6319c48f5851bd6c6f9cae68a |
| Source note | uspto-grants-1980_11 |