HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → 4-[[O-[N-Methyl-N-(phenylthiosulfenyl)carbamoyl]oximino]]-5-methyl-1,3-oxathiolane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | N-Methyl-N(Phenylthiosulfenyl)Carbamoyl Fluoride | HCID 23332999 | — |
| Reactant | N-(5-Methyl-1,3-oxathiolan-4-ylidene)hydroxylamine | HCID 71364792 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 4-[[O-[N-Methyl-N-(phenylthiosulfenyl)carbamoyl]oximino]]-5-methyl-1,3-oxathiolane | HCID 54520534 | — |
Reaction Steps
4-[[O-[N-Methyl-N-(phenylthiosulfenyl)carbamoyl]oximino]]-5-methyl-1,3-oxathiolane was prepared by the procedure described in Example I by reacting 5.0 g (0.0375 m) of 5-methyl-4-oximino-1,3-oxathiolane, 8.15 g (0.0375 m) of N-methyl-N-(phenylthiosulfenyl) carbamoyl fluoride and 3.79 g (0.0375 m) of triethylamine in 100 ml of dioxane. The crude residual oil was purified using silica gel column to yield 3.5 g of an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04232035 |
| Source dataset | uspto-grants-1980_11 |
| ORD ID | ord-08916eb5035f47c3abfb94a14a074343 |
| Source note | uspto-grants-1980_11 |