HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diisopropyl Ether → 4-[[O-[N-Methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl]oximino]]-5-methyl-1,3-oxathiolane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diisopropyl Ether | HCID 7914 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | N-methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl fluoride | HCID 23333002 | — |
| Reactant | N-(5-Methyl-1,3-oxathiolan-4-ylidene)hydroxylamine | HCID 71364792 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 4-[[O-[N-Methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl]oximino]]-5-methyl-1,3-oxathiolane | HCID 53755759 | — |
Reaction Steps
4-[[O-[N-Methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl]oximino]]-5-methyl-1,3-oxathiolane was prepared according to the procedure described in Example I by reacting 4.0 g (0.03 m) of 5-methyl-4-oximino-1,3-oxathiolane, 7.55 g (0.03 m) of N-methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl fluoride and 3.07 g (0.03 m) of triethylamine in 50 ml of dioxane. Addition of isopropyl ether and ethyl acetate to the residual oil and cooling yielded 2.37 g of a white solid, m.p. 71°-73° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04232035 |
| Source dataset | uspto-grants-1980_11 |
| ORD ID | ord-44878161322946f99f824831783d4e0b |
| Source note | uspto-grants-1980_11 |