Water → HCID 131727978, compound

HRID 2243781Notes

Reaction equation

HRID 2243781 reaction equation
[C:1]([NH2:5])(=[O:4])[CH:2]=[CH2:3].[CH2:6]([C:16](=C)[C:17]([NH2:19])=[O:18])CCCCCCCCC.[CH:21]([C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][C:24]=1[CH:29]=[CH2:30])=[CH2:22].O>C(O)C>[C:1]([NH2:5])(=[O:4])[CH:2]=[CH2:3].[CH2:30]([NH:19][C:17](=[O:18])[CH:16]=[CH2:6])[CH2:29][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:23][CH2:21][CH3:22]

Participants

6

Reactant 4

HCID 962WaterHCID 6579AcrylamideHCID 666661,2-DiethenylbenzeneHCID 212758792-Methylidenedodecanamide

Product 1

HCID 131727978HCID 131727978, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Polystyrenesulfonate (22.5 mmoles, 3.918 g), acrylamide (3.45 mmoles, 0.245 g), n-decylacrylamide (3.45 mmoles, 0.729 g) and divinylbenzene (0.6 mmoles, 85.5 microL) were dissolved in 15 mL ethanol and 5 mL water in a 40 mL vial fitted with a septa cap. The solution was degassed by bubbling nitrogen through and 1 mole % AIBN was added as a solution. The polymerization solution was further degassed and the placed in a heated reaction block at 60° C. for 18 h. A creamy yellow gel formed.

Workup

  1. customThe solution was degassed
  2. customby bubbling nitrogen through and 1 mole % AIBN
  3. additionwas added as a solution
  4. customThe polymerization solution was further degassed
  5. customthe placed in a heated reaction block at 60° C. for 18 h
  6. customA creamy yellow gel formed

Sources & evidence

ORD record
ord-c335425cea344fb0b6b1a151c69d1426
Source dataset
uspto-grants-2010_03
Patent number
US07678369B2

Reaction notes

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