HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → 2-[[O-[N-Methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl]oximino]]-3,5,5-trimethylthiazolidin-4-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | N-methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl fluoride | HCID 23333002 | — |
| Reactant | 2-(Hydroxyimino)-3,5,5-trimethyl-1,3-thiazolidin-4-one | HCID 71363389 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 2-[[O-[N-Methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl]oximino]]-3,5,5-trimethylthiazolidin-4-one | HCID 53901049 | — |
Reaction Steps
2-[[O-[N-Methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl]oximino]]-3,5,5-trimethylthiazolidin-4-one was prepared according to the procedure described in Example I, by reacting 5.0 g (0.0287 m) of 3,5,5-trimethyl-2-oximinothiazolidin-4-one, 7.22 g (0.0287 m) of N-methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl fluoride and 2.9 g (0.0287 m) of triethylamine in 50 ml of dioxane. 2-[[O-[N-Methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl]oximino]]-3,5,5-trimethylthiazolidin-4-one was crystallized from isopropyl ether to yield 5.9 g of a white solid, m.p. 74°-76° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04232035 |
| Source dataset | uspto-grants-1980_11 |
| ORD ID | ord-4c4caf07d5034b9ab3b74b9f120df43e |
| Source note | uspto-grants-1980_11 |