HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrazine hydrate (1:1) → (1S,8R)-1,11,11-Trimethyl-5-o-tolyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6-triene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Reactant | (+)-Camphorquinone | HCID 1549179 | — |
| Reactant | Dimethyl 2-o-methylphenyl-2-oxoethylphosphonate | HCID 14302186 | — |
| Product | (1S,8R)-1,11,11-Trimethyl-5-o-tolyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6-triene | HCID 67365823 | — |
Reaction Steps
yellow gum. MS (ESI): 278.2 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, (2-Oxo-2-o-tolyl-ethyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07678795B2 |
| Source dataset | uspto-grants-2010_03 |
| ORD ID | ord-d8426fb8e7674dc399a04586bbb0eb9d |
| Source note | uspto-grants-2010_03 |